石油化工安全环保技术 ›› 2020, Vol. 36 ›› Issue (2): 55-58.

• 清洁生产与综合治理 • 上一篇    

成品油库污水深度处理中试研究

姚 猛1,凌二锁2,徐知雄2,黄 斌2   

  1. 1. 中国石油化工股份有限公司青岛安全工程研究院,山东 青岛 266071 ;
    2. 苏州科环环保科技有限公司,江苏 苏州 215300
  • 收稿日期:2019-01-03 出版日期:2020-04-20 发布日期:2020-05-15
  • 通讯作者: 姚猛 E-mail: yaom.qday@sinopec.com
  • 作者简介:姚猛,男,2009 年毕业于苏州科技大学环境 工程专业,硕士,主要从事环境风险、环境安全领域的 研究和管理工作,工程师。电话:0532-83786980,E-mail: yaom.qday@sinopec.com

Pilot Study on Advanced Treatment of Sewage from Product Oil Depots

Yao Meng1, Ling Ersuo2, Xu Zhixiong2, Huang Bin2   

  1. 1. SINOPEC Qingdao Safety Engineering Institute, Qingdao, Shandong, 266071;
    2. Suzhou Koovin Environmental Protection Technology Co., Ltd., Suzhou, Jiangsu, 215300
  • Received:2019-01-03 Online:2020-04-20 Published:2020-05-15
  • Contact: Yao Meng E-mail: yaom.qday@sinopec.com

摘要: 对成品油库污水采用臭氧催化氧化—内循环BAF 组合工艺开展深度处理中试研究。调整臭 氧催化氧化段的臭氧投加量和HRT,考察污水处理效果,确定最佳工艺参数为:臭氧投加量=110 mg/L, HRT=2.5 h ;考察内循环BAF 不同HRT 下的污水处理效果,确定最佳HRT=3 h。臭氧催化氧化—内 循环BAF 组合工艺处理二级生化段MBR 出水,在进水COD>150 mg/L 的水质条件下,出水可以稳定 达到COD<80 mg/L,满足达标排放要求。臭氧催化氧化—合内循环BAF 组合工艺作为一种集高级氧 化和生化处理技术优势于一体的污水深度处理组合工艺,可以作为水运油库现有污水处理场提标改造 的参考工艺。

关键词: 油库污水, 深度处理, 臭氧催化氧化, 内循环BAF , 中试

Abstract: A pilot-scale study on advanced treatment of sewage from oil depots was carried out by combined process of ozone catalytic oxidation and internal circulation BAF. The ozone dosage and HRT in the ozone catalytic oxidation stage were adjusted to investigate the sewage treatment effect, and the optimum process parameters were determined as follows: ozone dosage=110 mg/L, HRT=2.5 h; the sewage treatment effect under different HRTs of internal circulation BAF was investigated, and the optimum HRT = 3 h was determined. The combined process of ozone catalytic oxidation and internal circulation BAF was used to treat MBR effluent from secondary biochemical stage. Under the condition of influent COD>150 mg/L, the effluent could reach COD<80 mg/L stably and meet the discharge requirements. As a combined advanced wastewater treatment process that sets advanced oxidation and biochemical treatment technology advantages in one, ozone catalytic oxidation combined with internal circulation BAF can be used as a reference process for upgrading the existing sewage treatment plants of water transport oil depots.

Key words: oil depot sewage, advanced treatment, ozone catalytic oxidation, internal circulation BAF, pilot test