石油化工安全环保技术 ›› 2024, Vol. 40 ›› Issue (4): 59-62.

• 清洁生产与综合治理 • 上一篇    

减少大型低温乙烯球罐预冷过程中VOCS 排放

李翠芳   

  1. 榆林市生态环境局横山分局(横山区环境监测站),陕西 榆林 719000
  • 收稿日期:2024-04-18 接受日期:2024-07-15 出版日期:2024-08-20 发布日期:2024-08-28
  • 作者简介:李翠芳,女,2014 年毕业于浙江海洋大学环境工程专业,现从事基层环境管理工作,助理工程师,E-mail:861063451@qq.com

Reduce VOCs Emissions During Pre-Cooling of Large Low-Temperature Ethylene Storage Tanks

Li Cuifang   

  1. Hengshan ecological and environment bureau of Yulin ( Environmental monitoring station of Hengshan),Yulin,Shaanxi,719000
  • Received:2024-04-18 Accepted:2024-07-15 Online:2024-08-20 Published:2024-08-28

摘要: 对某石化企业乙烯罐区3000m3 低温乙烯球罐预冷过程的工艺操作进行了简要介绍,针对乙烯球罐需要预冷至-30℃以下才能接料投用的苛刻工艺条件及预冷操作的技术难题和安全环保风险,在理论分析可行的基础上,提出将预冷方式由“插底管进液”改为“顶部喷洒液滴”。实践证明,顶部喷洒液滴的预冷方式将球罐预冷时间由56h 缩短至12h,减少了乙烯等挥发性有机物(VOCS)向火炬排放约30t,实现了碳减排和清洁生产目的。同时,也消除了因罐顶与罐底温差大导致球罐材质发生脆裂泄漏而引发的安全环保风险。

关键词: 低温乙烯球罐, 预冷, 温差, 脆裂泄漏, VOCS

Abstract: In view of the harsh process conditions of ethylene spherical tank that needs to be pre-cooled to below -30℃ before receiving materials and the safety and environmental protection risks of the pre-cooling operation, on the basis of theoretical analysis and feasibility, it is proposed to change the pre-cooling method from "bottom tube inlet" to "top spraying droplets" in view of the harsh process conditions of ethylene spherical tank that need to be pre-cooled to below -30°C before receiving materials and putting them into use. It has been proved in practice that the pre-cooling method of spraying droplets on the top shortens the pre-cooling time of the spherical tank from 56 hours to 12 hours, reduces the emission of volatile organic compounds (VOCs) such as ethylene to the flare by about 30 tons, and achieves the purpose of carbon emission reduction and cleaner production. At the same time, it also eliminates the safety and environmental protection risks caused by the brittle leakage of spherical tank material caused by the large temperature difference between the top and bottom of the tank.

Key words: Low-temperature ethylene spherical tank, Pre-cooling, Difference of temperature, Brittle leakag, VOCs