石油化工安全环保技术 ›› 2024, Vol. 40 ›› Issue (3): 57-61.

• 清洁生产与综合治理 • 上一篇    

气相色谱法测定不同行业废气中14 种挥发性卤代烃

王晓雯   

  1. 辽宁省大连生态环境监测中心,辽宁 大连 116023
  • 收稿日期:2023-05-11 接受日期:2024-05-15 出版日期:2024-06-20 发布日期:2024-06-25
  • 作者简介:王晓雯,女,2016 年毕业于大连海事大学环境工程专业,工程硕士,主要从事环境监测工作,高级工程师。电话:0411-84666030,E-mail :wxw0652@sina.com

Determination of 14 Kinds of Volatile Halogenated Hydrocarbons in Exhaust Gas by Gas Chromatography

Wang Xiaowen   

  1. Dalian Ecological Environment Monitoring Center of Liaoning Province, Dalian, Liaoning, 116023
  • Received:2023-05-11 Accepted:2024-05-15 Online:2024-06-20 Published:2024-06-25

摘要: 采用气袋采样,气相色谱法分析了固定污染源废气中的14 种挥发性卤代烃,各组分的曲线相关系数均大于0.99,方法检出限为0.0003~0.6 mg/m3 ;采用本方法对钢铁、石油化工厂和汽修厂等多家企业进行实样测试,各行业的加标样品相对标准偏差1.2%~8.8%,加标回收率为74.3%~116%。本方法的各项特性指标均达到预期要求,为分析固定污染源废气中的挥发性卤代烃提供了更为直接有效的方法。

关键词: 气袋, 气相色谱法, 废气, 挥发性卤代烃

Abstract: In this paper, 14 kinds of volatile halogenated hydrocarbons in the exhaust gas of stationary sources were analyzed by gas chromatography and air bag sampling. The curve correlation coefficient of each component was greater than 0.99; the detection limits of the method were from 0.0003 mg/m3 to 0.6 mg/m3. This method was adopted to test the real samples from iron and steel enterprises, petrochemical plants and auto repair factories. The relative standard deviation of spiked samples in various industries were from 1.2% to 8.8% and the recoveries were from 74.3% to 116%. All the characteristic indexes of this method can meet the expected requirements. This provides a more direct and effective method for the analysis of volatile halogenated hydrocarbons in the exhaust gas of stationary sources.

Key words: air bags, gas chromatography, exhaust gas, volatile halogenated hydrocarbons