石油化工安全环保技术 ›› 2024, Vol. 40 ›› Issue (1): 61-64.

• 工业污染防治与生态保护 • 上一篇    

含油污泥清洗剂配方筛选实验研究

  

  1. 辽河石油勘探局有限公司石油化工技术服务分公司,辽宁 盘锦 124010
  • 收稿日期:2022-11-02 出版日期:2024-02-20 发布日期:2024-03-14
  • 作者简介:王磊,男,毕业于东北石油大学化学工程与工艺专业,主要从事地面集输及采出液处理,包括原油破乳、含油污水、含油污泥处理技术工作,工程师。

Experimental Research on Formulation Screening of Oily Sludge Cleaning Agent

  1. Petrochemical Technology Service Branch of Liaohe Petroleum Exploration Bureau Co., Ltd., Panjin, Liaoning, 124010
  • Received:2022-11-02 Online:2024-02-20 Published:2024-03-14

摘要: 以某油泥处理厂的油泥为研究对象,以热化学清洗的方式,分别对比了单一化学药 剂、复配药剂的洗油效率,对实验温度、油泥与稀释水比例、搅拌时间和搅拌转速等实验条件进行 了系统分析。结果表明:单组化学组分中,Na2SiO3 · 9H2O 的洗油效率最高为 92.44% ;阴离子表面 活性剂 LAS 洗油效率较好,非离子表面活性剂 NP-10 的洗油效率最高,为 92.83%。复配药剂中, Na2SiO3 · 9H2O∶LAS∶NP-10 =6∶3∶1 时的清洗剂效率可达 96.58%。洗油效率随温度的升高而增大, 洗油效率随着液固比例的增加先增加后降低,合理的液固比例在 4∶1,最优实验温度为 80 ℃,搅拌时 间 30 min,洗油效率可达 96.58%。

Abstract: Taking the oily sludge of certain oily sludge treatment plant as the research object, the oil washing efficiency of single chemical agent and compound agent was compared by means of thermochemical cleaning. And the experimental conditions such as experimental temperature, proportion of oily sludge to prepared water, mixing time and mixing speed were analyzed systematically. The results indicated that the highest washing efficiency of Na2SiO3 · 9H2O is 92.44% among single chemical components; linear alkylbezene sulfonates (LAS) has better washing efficiency, and non-ionic surfactant NP-10 has the best washing efficiency, which is 92.83%. In the compound agent, the cleaning agent efficiency at Na2SiO3 · 9H2O:LAS:NP-10 =6:3:1 can reach 96.58%. The washing efficiency increases with the increase of temperature; with the increase of liquid-solid ratio, the oil washing efficiency first increases and then decreases. The reasonable liquid-solid ratio is 4:1; the optimal experimental temperature is 80 ℃ , and the stirring time is 30 minutes. The oil washing efficiency can reach 96.58%. 

Key words: oily sludge, sludge cleaning agent, cleaning agent compounding, experiment optimization