石油化工安全环保技术 ›› 2024, Vol. 40 ›› Issue (3): 29-32.

• 清洁生产与综合治理 • 上一篇    

有机金属超滤膜除油技术研究

倪福功,王国栋   

  1. 中国石油化工股份有限公司天津分公司,天津 300270
  • 收稿日期:2024-01-10 接受日期:2024-05-15 出版日期:2024-06-20 发布日期:2024-06-25
  • 作者简介:倪福功,男,1997 年毕业于天津理工大学工业电气自动化专业,现主要从事污水处理管理工作,工程师。电话:13821427389,E-mail: nifg126d@126.com

Research on Oil Removal Technology by Organic Metal Ultrafiltration Membrane

Ni Fugong, Wang Guodong   

  1. SINOPEC Tianjin Company, Tianjin, 300270
  • Received:2024-01-10 Accepted:2024-05-15 Online:2024-06-20 Published:2024-06-25

摘要: 有机金属超滤膜在进行油水分离过滤时,良好的亲水憎油性使得有机金属膜具有抗污染、不易污堵的特性。在开展的除油试验中,有机金属超滤膜除油装置在30LMH 的膜通量下可稳定运行1个月以上,且石油类和SS 去除率平均分别达76.8% 和76.6%,产水石油类、SS 稳定达标,最高仅分别为10.3mg/L、23mg/L,低于气浮工艺出水指标要求近50%。有机金属超滤膜除油装置在40LMH 的膜通量下,运行难度增加,通过CEB 与CIP 联合清洗可有效延长膜的稳定运行周期,保证系统的稳定运行。在30LMH 的膜通量下有机金属超滤膜工艺可替代传统的气浮处理工艺。

关键词: 有机金属材质, 超滤, 除油

Abstract: Organic metal ultrafiltration membranes have good hydrophilicity and hydrophobicity during oil-water separation and filtration, which make them resistant to pollution and less prone to clogging. In the oil removal experiment conducted by using organic metal ultrafiltration membrane, the oil removal device using organic metal ultrafiltration membrane can operate stably for more than one month at a membrane flux of 30LMH, and the average removal rates of petroleum and SS are 76.8% and 76.6% respectively. The produced water for petroleum and SS is stable and meets the standards, with the highest being only 10.3mg/L and 23mg/L respectively, which is nearly 50% lower than the effluent indicators required by the air flotation process. The operation difficulty of the oil removal device using organic metal ultrafiltration membrane increases at a membrane flux of 40LMH. The combined cleaning of CEB and CIP can effectively extend the stable operation cycle of the membrane and ensure the stable operation of the system. The organic metal ultrafiltration membrane process can replace the traditional air flotation treatment process at a membrane flux of 30LMH.

Key words: organic metal materials, ultrafiltration, oil removal