石油化工安全环保技术 ›› 2020, Vol. 36 ›› Issue (2): 42-44.

• 事故分析与预防 • 上一篇    

硫化铁的危害辨识及硫磺回收装置中典型事故分析

孟爱华   

  1. 中国石油天然气股份有限公司锦州石化分公司,辽宁 锦州 121001
  • 收稿日期:2019-03-15 出版日期:2020-04-20 发布日期:2020-05-15
  • 通讯作者: 孟爱华 E-mail :mengaihua@ petrochina.com.cn
  • 作者简介:孟爱华,女,2000 年毕业于大庆石油学院炼 油与化工专业,学士,主要从事统计核算和技术分析工 作,工程师。电话:17604067180 ,E-mail :mengaihua@ petrochina.com.cn

Hazard Identification of Iron Sulfide and Analysis of Typical Accidents in Sulfur Recovery Unit

Meng Aihua   

  1. PetroChina Jinzhou Petrochemical Company, Jinzhou, Liaoning, 121001
  • Received:2019-03-15 Online:2020-04-20 Published:2020-05-15
  • Contact: Meng Aihua E-mail :mengaihua@ petrochina.com.cn

摘要: 在炼油化工装置中,凡涉及到含硫原油、含硫油品的工艺管线、工艺设备均存在不同程 度的硫腐蚀,随着炼制高含硫原油加工量的增加,生产运行周期的延长,硫对设备腐蚀加剧,生成的 硫化产物增加,一旦装置停工检修或开孔检查,塔、容器、工艺管线中的硫化铁难免造成火灾或爆炸 事故。对硫化铁的产生、造成火灾或爆炸的原因进行了危害辨识,对硫磺回收装置停产检修过程中因 硫化铁的存在发生的典型事故进行了分析。

关键词: 硫化铁, 危害, 辨识, 硫磺

Abstract: In oil refining chemical plant, involving the sulfur crude oil, oil of sulfur process pipeline, process equipment, there are different levels of sulfur corrosion, with the increase of refining high sulfur crude oil processing capacity, the extension of production cycle, the sulfur of equipment corrosion intensifies, the generated sulfide product, once the device breakdown maintenance or opening inspection, tower, containers, process pipeline of iron sulfide unavoidably cause fire or explosion. In this paper, the hazard identification of the production of iron sulfide, the causes of fire or explosion is carried out, and the typical accidents due to the presence of iron sulfide in the shutdown and maintenance of sulfur recovery devices are briefly described.

Key words: iron sulfide, harm, identification, sulfur